aqueous skin and hair cleaning compositions comprising biotensive agents

专利摘要:
Abstract Aqueous Skin and Hair Cleaning Compositions comprising Biotensives The present invention is directed to compositions comprising water, at least one biotensive agent and at least one fatty acid, which are characterized by the fact that the sum fraction of all surfactants in the composition is 1 to 30 wt%, and the fatty acid fraction, based on the sum of the fatty acids and surfactants, is 0.1 to 20 wt%, and their use as, or for production bath additives, shower gel, shampoos, conditioners, body or skin cleansers.
公开号:BR112014016225B1
申请号:R112014016225-5
申请日:2012-12-11
公开日:2018-12-26
发明作者:Petra Allef；Christian Hartung；Martin Schilling
申请人:Evonik Degussa Gmbh；
IPC主号:

专利说明:

AQUEOUS SKIN AND HAIR CLEANING COMPOSITIONS UNDERSTANDING BIOTENSOACTIVES [001] The present invention is directed to compositions, in particular, skin and hair cleaning compositions, particularly preferably formulations for the cleaning and care of parts of the human or animal body, in skin and hair for leather or feathers. The compositions according to the invention comprise one or more biotensoatives, one or more fatty acids and water. The compositions can be, for example, cleansing or care formulations, such as, for example, shampoos, conditioners, shower gels, body cleansing compositions or skin cleansing compositions.
[002] There has long been a need to provide gentle cleansing compositions that are especially gentle to skin and hair. Such cleaning compositions should not only be gentle on the skin and hair, but also have more desirable properties, such as, for example, good storage stability and good foaming behavior. In addition, there is a greater need for surfactants, which are completely based on renewable raw materials and can be produced sustainably, through mild conditions (for example, through fermentation).
[003] Several mild surfactant systems have already been proposed with which it has been attempted to produce corresponding cleaning compositions. Often, the mild surfactant systems exhibited a lower foaming capacity, meaning that greater
2/83 addition of a surfactant system was necessary, which in turn led to less smoothness of the product.
[004] Suitable surfactant systems that lead to mild cleaning compositions, with usable foam behavior that have been proposed, are those that comprise sulfosuccinates as surfactants in combination with amphoteric surfactants. Such systems are described, inter alia, in EP 1771148 and EP 1771538.
[005] A disadvantage of sulfosuccinate systems was their unpredictable behavior with regard to adjusting viscosity and storage stability, particularly their tendency to gel. According to EP 1771538, sulfosuccinate hydrolysis products are responsible for the poor storage stability of such cleaning compositions.
[006] The prior art describes the use of so-called biotensoatives for the production of skin and / or hair cleaning compositions and as a cleaning agent and textile detergent.
[007] US 7,985,722 describes formulations that have rhamnolipids and their use as cleaning, disinfecting or deodorizing compositions. In the examples of such formulations, which have 5% crude ramnolipid and water and ethanol as the solvent / vehicle, they are used, for example, as a cleaning composition / shampoo for pets. For use in people, a 2% solution of crude ramnolipid in water / ethanol was used. The ramnolipid was added to a shampoo-based formulation. In a concentration range of 0.01 to 35% ramnolipid
3/83 concentrated crude, redness of the skin was observed here (example 4).
[008] US 7,556,654 describes organic cleaning products which have biotensoactives, in particular soforolipids, and one or more enzymes.
[009] EP 0 499 434 describes compositions for washing textiles, dishes and surfaces at home, comprising one or more glycolipid biotensoatives, in particular soforolipids, glucose lipids, cellobiose lipids, trehalose lipids and ramnolipids. Here, the examples describe a particularly good washing / cleaning performance if mixtures of glycolipid biotensoactive, in particular ramnolipids, are used with non-glycolipid biotensoactive, such as, for example, ethoxylated dodecyl alcohol or di-C8-sulfosuccinate. The non-glycolipid biotensoactive is present in the lamellar phase, and the glycolipid biotensoactive is present in the micellar phase.
[010] that have at least
EP 1 445 302 describes cleaning compositions minus a glycolipid biotensoactive and a non-glycolipid biotensoactive, where at least one non-glycolipid biotensoactive is present in the micellar phase.
[011] EP 1 411 111 describes biodegradable low foaming detergent compositions, which have a mixture of two soforolipids, as well as auxiliary detergent components, selected from enzyme, oxygen bleach, bleach activator, alkaline development substance, sequestering , fluid reforming agent and neutral inorganic salt.
4/83 [012] WO 03/006146 discloses aqueous preparations comprising surfactant fermentation products and nonionic surfactants, and their use for the production of cosmetic preparations.
[013] An object of the present invention is to provide compositions, in particular hair and skin cleansing compositions, particularly preferably formulations for the cleaning and care of parts of the human or animal body, in particular skin and hair or leather or feathers, which do not have one or more of the disadvantages of known formulations. The compositions according to the invention should preferably be biodegradable to the greatest possible extent, easily compatible, that is, cause, in particular, only a slight, if any, redness of the skin and / or eyes, have a good care benefit of the skin and / or be based, as much as possible entirely of natural raw materials.
[014] Surprisingly, it was found that the compositions, as defined in the claims and described below, reach one or more of the objects indicated.
[015] Unexpectedly, in the hand washing test (HWT), it was found that the present additionally fatty acid (oleic acid) has a positive effect and, contrary to expectations, has no significant effects on the foam or properties thickeners in the surfactant solution.
[016] Therefore, the present invention provides compositions comprising water, at least one biotensoactive and at least one fatty acid, which are characterized by the fact that the fraction of the sum of all surfactants in the compositions is 5 to 20 % in
5/83 weight, and that the fatty acid fraction, based on the sum of the fatty acids and surfactants, is 0.1 to 20% by weight.
[017] In addition, the present invention provides the use of the compositions according to the invention, as or for the production of bath additives, shower gels, shampoos, conditioners, impregnating lotions for wet wipes, skin cleaning compositions. body or skin cleansing compositions.
[018] An advantage of the composition according to the invention is that the fraction of surfactants present in it, which is based on renewable raw materials, is preferably greater than 50% by weight, based on the total amount of surfactants.
[019] Another advantage of the composition according to the invention is that sugars or sugars and glycerides and / or fatty acids can be used as raw materials for biotensoatives.
[020] Another advantage of the composition according to the invention is that it is very smooth.
[021] It is also an advantage that many of the compositions according to the invention achieve surprisingly good performance in a panel test (for example, skin emollient properties) compared to formulations with surfactants that are not a biotensive and, at the same time, they often have a negligible effect on viscosity and virtually no effect on the foaming capacity of the surfactant mixtures investigated.
[022] The compositions according to the invention, and their uses are described below by way of
6/83 example, without any intention of limiting the invention to these exemplary embodiments. Whenever the respective ranges, general formulas or classes of compounds are presented below, then these are intended to include not only the corresponding ranges or groups of compounds that are explicitly mentioned, but also all ranges of parts and groups of parts of compounds that can be obtained by removing individual values (ranges) or compounds. Wherever the documents cited are within the scope of this description, then, their contents, in particular with respect to the background material to which reference is made, are considered as belonging in their entirety to the content of the disclosure of the present invention. . Where average values are shown below, then, unless otherwise stated, these are weighted average numerical values. Unless otherwise stated, percentages are given as a percentage by weight. Whenever the measured values are given below, then, unless otherwise stated, these were determined at a temperature of 25 ° C and a pressure of 1013 mbar.
[023] The compositions according to the invention, comprising water, at least one biotensoactive and at least one fatty acid, are characterized by the fact that the fraction of the sum of all surfactants in the compositions according to the invention is from 0.1 to 30% by weight, preferably 1 to 25% by weight, preferably 2.5 to 20% by weight and especially preferably from 10 to 20% by weight, and that the fatty acid fraction, with based on the sum of
7/83 fatty acids and surfactants, is 0.01 to 20% by weight, preferably 0.1 to 15 and preferably from 1 to 10% by weight.
[024] The fraction of biotensoactives in the compositions according to the invention is preferably from 0.1 to 30% by weight, preferably from 0.5 to 20% by weight and particularly preferably from 0.75 to 10% by weight , based on the total composition.
[025] In the context of the present invention, biotensoatives are understood to mean all glycolipids produced by fermentation.
[026] The raw materials for the production of biotensoatives that can be used are carbohydrates, in particular sugars, such as, for example, sources of glucose and / or lipophilic carbon, such as fats, oils, partial glycerides, fatty acids , fatty alcohols, long chain saturated or unsaturated hydrocarbons. Preferably, in the compositions according to the invention, no biotensive agents are present which are not produced by fermentation of glycolipids, such as, for example, lipoproteins.
[027] Preferably, the composition according to the invention has, as biotensoactives, ramnolipids, soforolipids, glycoselipids, celluloselipids and / or trehalosipids, preferably ramnolipids and / or soforolipids. Biotensics, in particular glycolipidic surfactants, can be produced, for example, as in EP 0 499 434, US 7,985,722, WO 03/006146, JP 60 183032, DE 19648439, DE 19600743, DE 19600743, JP 01 304034, CN 1,337,439, JP 2006 274233, KR 2004033376, JP 2006 083238, JP 2006 070231, WO 03/002700, FR 2740779, DE 2939519, US
8/83
7,556,654, FR 2855752, EP 1445302, JP 2008 062179 and JP 2007
181789 or the appropriate documents there may be purchased, cited. Biotensics for example, from Soliance,
France.
[028]
Preferably, the composition according to the invention has, as biotensoatives, ramnolipids, in particular mono-, di- or polyamynolipids and / or soforolipids. In particular, the composition according to the invention has one or more of the ramnolipids and / or serofolipids described in
EP 1 445 302 A with formulas (I), (II) or (III).
[029]
The fatty acids that may be present in the compositions according to the invention are all aliphatic carboxylic acids, branched or unbranched, saturated or unsaturated, or known, or di-, polyhydroxycarboxylic acids, or oligomers thereof. Preferably, the composition according to the invention comprises one or more (hydroxy) fatty acids selected from the group comprising formic acid, acetic acid, propionic acid, butyric acid, valeric acid, hexanoic acid (capranoic acid), heptanoic acid (enanthic acid, enanthic acid), octanoic acid (caprylic acid), pelargonic acid (nonanoic acid), decanoic acid (capric acid), undecanoic acid, dodecanoic acid (lauric acid), tridecanoic acid, tetradecanoic acid (myristic acid) pentadecanoic acid , palmitic acid (hexadecanoic acid), marginic acid (heptadecanoic acid), stearic acid (octadecanoic acid), nonadecanoic acid, arachic acid (eicosanoic acid), behenic acid (docosanoic acid),
9/83 tetracosanoic acid (lignoceric acid), kerotic acid (hexacosanoic acid), triacontanoic acid (melissic acid), isobutyric acid (2-methylpropanoic acid), 3-methylbutyric acid (isovaleric acid, 3-methylbutanoic acid), tuberculosic acid (10 ), acrylic acid (propenoic acid) butenoic acid, [crotonic acid, (2E) -but-2enoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) octadec-9 acid -enoic acid], elaidic acid [(9E) -octadec-9-enoic acid], erucic acid [(13Z) docos-13-enoic acid], sorbic acid [(2E, 4E) -hexa-2-4dienoic acid], linoleic acid [(9Z, 12Z) -octadeca-9,12dienoic acid], linolenic acid [(9Z, 12Z, 15Z) -octadeca9,12,15-trienoic acid], elaeostearic acid [(9Z, 11E, 13E) - octadeca-9,11,13-trienoic], arachidonic acid [(5Z, 8Z, 11Z, 14Z) -icosa-5,8,11,14-tetraenoic acid], eicosapentaenoic acid [(5Z, 8Z, 11Z, 14Z, 17Z) -icosa5,8,11,14,17-pentaenoic], clupanodonic acid [(4Z, 8Z, 12Z, 15Z, 19Z) -docosa-4,8,12,15,19-pentaenoic acid ], mandelic acid, lactic acid, hydroxysuccinic acid, citric acid, tartaric acid, β-hydroxydecanoic acid or its dimer, other fruit acids, ricinoleic acid, and humic acids
Preferably, the composition according to the invention from capróico), enantico), pelargonic capric), acid comprises one or more of valeric acid, heptanoic acid octanoic acid (acidic acid (acid (nonanoic acid), dodecanoic acid (acid selected fatty acids hexanoic (enanic acid, caprylic acid), decanoic acid (lauric acid), tetradecanoic acid (myristic acid), palmitic acid (acid
10/83 hexadecanoic), marginal acid (heptadecanoic acid), stearic acid (octadecanoic acid), arachic acid (eicosanoic acid), behenic acid (docosanoic acid), tetracosanoic acid (lignoceric acid), cerotic acid (hexacosanoic acid), triac acid (melissic acid), tuberculosteic acid (10methyloctadecanoic acid), palmitoleic acid [(9Z) hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9enoic acid], elaidic acid [(9E) -octadec-9 acid -enoic], erucic acid [(13Z) -docos-13-enoic acid], sorbic acid [(2E, 4E) -hexa-2,4-dienoic acid], linoleic acid [(9Z, 12Z) -octadeca- 9,12-dienoic], linolenic acid [(9Z, 12Z, 15Z) -octadeca-9,12,15-trenoic acid], elaeostearic acid [(9Z, 11E, 13E) -octadeca-9,11,13trienic acid] , arachidonic acid [(5Z, 8Z, 11Z, 14Z) icosa-5,8,11,14-tetraenoic acid], eicosapentaenoic acid [(5Z, 8Z, 11Z, 14Z, 17Z) -icosa-5,8,11 , 14,17pentaeno ico] and clupanodonic acid [(4Z, 8Z, 12Z, 15Z, 19Z) -docosa-4,8,12,15,19-pentaenoic acid]. In the composition according to the invention, fatty acids are particularly preferably present which are based on renewable raw materials, in particular fats or oils of animal or vegetable origin, in particular dimeric βhydroxydecanoic acid, oleic acid, palmitic acid , stearic acid and / or linoleic acid. The fatty acid fraction, which is not based on renewable raw materials, is, based on the total sum of the fatty acids present, preferably less than 10% by weight, preferably less than 1% by weight and particularly preferably less than 0.1% by weight.
11/83 [030] The fatty acids present in the composition according to the invention can in particular be those that are optionally used in the process for the production of the biotensoactive and / or optionally are produced as a by-product. In the case of using a reaction mixture, which is produced during the production of the biotensoactive and has fatty acids, it is possible to dispense with a supplementary addition of fatty acid if the fatty acid fraction corresponds to the above mentioned limits. In addition, if the fatty acid is produced in adequate quantities (as claimed) in the reaction mixture, during the production of the biotensoactive, it is possible to dispense with the complex removal of this fatty acid.
[031] It may be advantageous if the composition according to the invention furthermore has at least one surfactant, which is not a bio-surfactant. The weight ratio of biotensoactives to surfactants that are not a biotensoactive in the composition according to the invention can be> 1: 1 or 1: 1. Preferably, the weight ratio of biotensives to surfactants, which are not a biotensives is> 1: 1 or <1: 1, preferably> 1: 1.
[032] As surfactants that are not biotensoactive, the composition according to the invention can have all suitable known surfactants, especially for cosmetic formulations. Preference is given to the use of such surfactants as described, for example, in DE 102005011785, EP 2000124 and WO 2010/108756.
[033] Preferably, the composition according to the invention has, as surfactants that are not biotensoactives, surfactants with an anionic, amphoteric /
12/83 ampholytic and / or zwitterionic. Typical examples of mild surfactants, that is, particularly compatible with the skin, are fatty polyglycolic ether sulfates, monoglyceride sulfates, alkyl sulfates, mono- and / or dialkyl sulfosuccinates, fatty acid isethionates, acid sarcosinates fatty, fatty acid taurides, fatty acid glutamates, ethercarboxylic acids, alkyl oligoglucosides, alkyl polyglucosides, fatty acid glucamides, alkylamidobetaines and / or alkylbetaines.
[034] Amphoteric surfactants that may be present are, for example, betaines, amfoacetates or amphopropionates, such as, for example, substances such as N-alkyl-N, N-dimethylammonium glycinates, for example, cocoalkyl dimethylammonium glycinates, Nacylaminopropyl glycinates N, N-dimethylammonium, for example, cocoacylaminopropyl dimethylammonium glycinate, and 2-alkyl-3-carboxylmethyl-3-hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group, as well as cocoacylaminoethyl-hydroxyethyl carboxy glycinate.
[035] Ampholytic surfactants that may be present are those surfactant compounds that, in addition to a Ce / ie-a-alkyl or -acyl group in the molecule, contain at least one free amino group and at least one COOH or SO3H group and are capable to form internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-Nalkylamidopropylglycines, N-alkyltaurines, N
13/83 alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 18 carbon atoms in the alkyl group. Other examples of ampholytic surfactants are N-cocoalquilaminopropionato, and cocoacilaminoetilaminopropionato Ci2 / i8 ^- a-cilsarcosina.
[036] Preferred anionic surfactants are, for example, salts of different cations (sodium, ammonium or others) of cocoylglutamates, lauryl glucose carboxylate, etc. Zwitterionic surfactants, which may be present in the formulation cocamidopropylbetaine Amphoteric amphoteric surfactants such as cocoamfodiacetate [037] It comprises at least comprises alkyl sulfates, mono- and / or dialkyl oligosaccharides, fatty acid sarcosinates [038] The ones do not comprise polyethylene glycol.
[039] People can have dyes.
they are, for example, cosmetic purposes, publication of less or preferred disodium cocoamfoacetate.
preference is given to the surfactants in the lauryl ether, alkyl ether group, or are, for example, cocoamidopropylsultaine. they are, in particular, such as sodium or that which sulfates of alkyl amidobetaine sulfosuccinates or as non-biotensive.
particularly preferred which have sulphates or surfactant compositions compositions according to the invention The dyes that can be used the approved and suitable substances as they are listed, for example, in Kosmetische Fãrbemittel [cosmetic dyes] of the Dyestuff Commission of the German Research Society ,
Verlag Chemie, Weinheim, 1984, pages 81-106.
14/83 [040] It can be advantageous if the compositions according to the invention have one or more natural dyes. Within the context of the present invention, natural dyes are understood to mean mineral dyes or dyes obtained from plants or animals. All natural dyes can be used in the compositions according to the invention. Preferred natural dyes are, for example, indigo, lawson, purple, carmine, kermes, alizarin, pastel, crocetina, brasilin, saffron, crocetine, curcumia, curcumin, orlean, bixin, annatto, anthocyanins, betanine, capsanthin, carotene, chlorophyll, carminic acid, lutein, xanthophyll, lycopene, vegetable black or caramel. Particular preference is given to the use of natural dyes that are obtained from plants or animals.
[041] Natural substances especially preferably used are bixin (E 160b), anthocyanins (E 163), bethanine (E 162), capsanthin (E 160c), carotene (E 160a), chlorophylls (E 140), curcumin (E 100 ), carminic acid (E 120), lutein (E 161b), xanthophyll, lycopene (E 160d), vegetable black (E 153) and / or caramel (E 150a).
[042] The composition according to the invention particularly preferably has only natural dyes as dyes.
[043] The fraction of dyes, preferably natural dyes, in the compositions according to the invention is preferably from 0.001 to 1% by weight.
[044] The use of natural dyes obtains better biodegradability and tolerability (smoothness) of the composition according to the invention.
15/83 [045] The composition according to the invention may have preservatives, for example, those listed in the EC regulation (Regulation (EC) No. 1223/2009 of the European Parliament and of the Council, of 30 November 2009 relating to cosmetic products, Annex V). Preferred compositions according to the invention are those that comprise, as preservatives, one or a combination of the following substances: benzyl alcohol, sodium benzoate, potassium sorbate, DMDM hydantoin, formic acid, benzoic acid or polyaminopropyl biguanide. Particularly preferred compositions, however, are those that are free of preservatives, in particular free of those according to EU regulation.
[046] It may be advantageous if the composition according to the invention comprises propylene glycol, urea, glycerol, essential oils, phenylethyl alcohol and / or ethanol. Preferably, the fraction of the sum of propylene glycol, urea, glycerol, essential oils, phenylethyl alcohol and ethanol in the composition is 0.01 to 15% by weight, preferably 0.1 to 10% by weight. By using one or more of the specified substances, it is possible to prevent or at least reduce the increase in the germ count.
[047] It can be advantageous if the composition according to the invention comprises at least one thickener. The thickener fraction in the composition is preferably from 0.05 to 20% by weight, preferably from 0.1 to 10% by weight and especially preferably from 0.5 to 5% by weight, based on the composition.
[048] As a thickener, the composition according to the invention preferably has one or more thickeners, such as
16/83 such as those of relatively high molecular weight, preferably PEG> 10, preferably> 100, polyethylene glycol mono- and diesters of fatty acids, such as, for example, PEG 18 glyceryl oleate, PEG 55 oleate polypropylene glycol, PEG 120 methylglucose dioleate or PEG 200 or hydrogenated glyceryl webbing, preferably PEG-free thickeners, preferably selected from polysaccharides, in particular xanthan gum, guar and guar derivatives, agar agar, alginates and tyloses , cellulose or cellulose derivatives, such as, for example, ethylcellulose, carboxymethylcellulose, hydroxyethylcellulose or hydroxomethylpropylcellulose, alkyl modified sugar derivatives, such as, for example, cetylhydroxyethylcellulose, carbomers (crosslinked polyacrylates), polyacrylamides, polyvinyl alcohol and polyvinyl alcohol of ethoxylated fatty acids, fatty acid esters with polyols, such as, for example, pentaerythr tol or trimethylolpropane, fatty alcohol ethoxylates and alkyl oligoglycosides.
[049] Preferred compositions according to the invention are those that have a combination of a polymeric thickener for the water phase and a polymeric thickener for the oil phase.
[050] Particularly preferred compositions are those in which thickeners exclusively (that is, at least 90% by weight, preferably 100% by weight, of the thickeners present) are present, which are based, in part or completely, on in particular, completely from renewable raw materials, such as gum
17/83 xanthan, guar and guar derivatives, agar agar, alginates and tiloses, cellulose or cellulose derivatives.
[051] It can be advantageous if the composition according to the invention has perfume oils or fragrances. Perfume oils that can be used are all known perfume oils and, in particular, perfume oils suitable for the production of cosmetic formulations. Suitable perfume oils can be found, for example, in the product catalogs of well-known manufacturers, such as Symrise, Frey & Lau or IFF. Preferably, the composition according to the invention has perfume or fragrance oils, where the fraction of natural fragrances, based on the total number of fragrances in perfume oils, is at least 50% by weight, preferably at least 75% and preferably at least 95% by weight.
[052] Natural fragrances that can be used are, for example, flower extracts (lily, lavender, rose, jasmine, neroli, ylang ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, cumin , juniper), fruit peels (bergamot, lemon, orange), roots (apple, angelica, celery, cardamom, costus, iris, thyme), needles and branches (firs, pines, dwarf pines), resins and balms (galbanum, elemi, benzoin, myrrh, olibanum, opoponax). Raw materials of animal origin are also suitable as natural fragrances, such as, for example, civet and castor. Essential oils are also suitable as perfume oils, such as, for example, sage oil, chamomile oil, clove oil, melissa oil, mint oil, cinnamon leaf oil, linden flower oil,
18/83 juniper berries, vetiver oil, galbanum, labdanum oil, bergamot oil, lemon oil, oil
frankincense oil, i oil lavender, oil in and tangerine, oil in
sage.
orange, geranium oil or [053] oil
The compositions according to the invention may comprise, as additional components, in particular, for example, those which are, for example, selected from the group of emollients, emulsifiers, viscosity regulators / stabilizers, UV photoprotective filters, antioxidants, agents fillers and solids, film-forming agents, pearl additives, active antiperspirant deodorant ingredients, insect repellents, self-tanning agents, conditioners, active ingredients (cosmetics), care additives, super-greasing agents, solubility promoters (solubilizers), pearlescent agents and solvents, with the proviso that the specified components are not identical for biotensoactives, surfactants, thickeners. Substances that can be used as exemplary representatives of the individual groups are known to the person skilled in the art and can be found, for example, in patent applications DE 102008001788 Al, DE 102005011785 Al and EP 2000124 A. The substances specified therein as being preferred should also be found. be considered as preferred substances within the scope of the present invention. Patent applications are hereby incorporated by reference and thus form part of the disclosure. Preferred compositions according to the invention have in particular solubility promoters (solubilizers) for insoluble substances
19/83 in water and active ingredients for skin and hair care, such as overfatting agents. The fraction of the sum of the other components specified in this section in the composition according to the invention is preferably 3 to 50% by weight, preferably 5 to 25% by weight.
[054] Within the context of the present invention, a solubilizer or solubility promoter is the term used to refer to a substance that is capable of bringing the water-insoluble compounds into solution, as clearly as possible in aqueous systems. According to the generally accepted postulate, in this process, aggregates such as micelles are formed into whose structures the hydrophobic substances are integrated. The formation of a microemulsion, that is, a thermodynamically stable mixture of water (aqueous solution), an oil (water immiscible substance) and a solubilizer or solubility promoter is optimal. Typical solubilizers are ethoxylated fatty derivatives and polyglycerol fatty acid esters.
[055] Active care ingredients or emollients that may be used are, in particular, for example, isopropyl myristate, sucrose cocoate, ethoxylated glycerol fatty acid esters, such as, for example, PEG 7 glyceryl cocoate (such as eg TEGOSOFT® GC available from Evonik Industries AG), polyglycerol fatty acid esters, such as polyglyceryl 3 caprate or cationic polymers, such as, for example, polyquaternium 7. These are also referred to as overfat agents .
[056] The particularly preferred compositions according to the invention are free of polyethylene glycol (PEG) and / or its derivatives and are preferably also free of propylene glycol (PPG) and / or its derivatives.
[057] Even more particularly preferred compositions according to the invention are free of sulfates and, in addition, free of polyethylene glycol (PEG) and / or its derivatives and propylene glycol (PPG) and / or its derivatives.
[058] The compositions according to the invention preferably have a pH, determined by means of a pH meter of the type of Sartorius PB 11, from 5 to 8.
[059] Preferred compositions have a viscosity, determined at 25 ° C using a DV-I Prime Brookfield type 500 viscometer at 20000 mPas.
[060] The compositions according to the invention are preferably a body, skin or hair treatment composition for treating people and / or animals, in particular people and mammals.
[061] A composition according to the invention can be, in particular, a shampoo, a conditioner, a shower gel, a body cleansing composition or a skin cleansing composition. Compositions according to the invention are preferably liquid, cosmetic, dermatological or pharmaceutical body cleansing compositions, in particular shower baths and gels, bath formulations, liquid soaps and shampoos, or are used to produce these products / formulations.
[062] The compositions according to the invention can be, in particular, a bath additive, shampoo, conditioner, shower gel, body cleanser,
21/83 impregnation solutions for cleaning wipes or skin cleansers or be used for the production of one or more of these products.
[063] Particularly preferred compositions are those that combine some or all of the preferred characteristics mentioned above.
[064] The present invention is described by way of example in the examples listed below, without any intention of limiting the invention, the scope of which arises from the entire description and in the claims, for the embodiments specified in the examples.
Examples [065] Unless otherwise stated, all concentrations of the application examples are given in percent by weight. Usual formulation methods known to the person skilled in the art have been used to prepare the compositions.
Product example 1: Serofolipid:
[066] Serofolipid was prepared by fermentation with the yeast Candida bombicola based on the substrates glucose, sunflower oil, rapeseed oil or olive oil (comprising predominantly oleic acid as a fatty acid fraction).
[067] The growth medium comprised the following components:
- 10.0 g / 1 glucose ((D) + -glucose · 1 H ₂ 0)
- 7.5 g / 1 YNB (Yeast Nitrogen Base)
- 2.0 g / 1 yeast extract
22/83 [068] 1,1 1 of the medium were autoclaved in a fermenter with an operational volume of 2 1 and inoculated with a pre-culture, which was in the exponential phase, from the same medium. The temperature was adjusted to 30 ° C. PO2 was maintained through the stirring speed at 30% relative saturation over gas with air; the agitation speed, however, was never less than 200 rpm. During the biomass formation phase, the pH dropped to 3.5 and was maintained at this value by the addition of NaOH. After the biomass formation phase was complete (the consumption of glucose present, characterized by an increase in pO ₂ , or a decrease in pCO ₂ ), the product formation phase was initiated by the addition of 150 g of corresponding oil, 200 ml of a 750 g / 1 glucose solution and 10 ml of a 150 g / 1 yeast extract solution. The end of the product formation phase was characterized by a renewed increase in pO2. After fermentation was complete, the mixture was autoclaved, during which the crude product phase stabilized out. The crude product phase was washed with water. The product phase was then extracted with ethyl acetate and then the solvent was removed in vacuo. Analysis by HPLC-MS and NMR revealed that the product comprised, in addition to the serofolipid, also about 10% by weight, of unreacted free fatty acids (in particular, oleic acid), based on serofolipids. Residual fatty acid was removed from the product by means of multiple extraction with n-hexane, at pH 3, so that the residual amount of free fatty acids was <0.1% by weight (HPLC). A colorless solid was obtained.
Product example lb: Sorofolipid + 10% oleic acid:
23/83 [069] Example of the product la was mixed with 10% by weight of technical grade oleic acid (Cremer Oleo GmbH und Co. KG, Germany).
Product example 2a: Ramnolipideo:
[070] Product obtained from Ramnolipid, Inc.,
USA, as a 25% strength aqueous solution. HPLC analysis ensures that no free fatty acids (ie, <0.1% by weight, based on the total composition of the product) are contained as a secondary component.
Product example 2b: Ramnolipid + 10% oleic acid:
[071] Example of product 2a was mixed with 10% by weight of technical grade oleic acid with respect to ramnolipid.
Skin compatibility according to the RBC test:
[072] In the so-called RBC test (Cell Test
Blood Red, see W.J.W. Pape, U. Pfannenbecker, U. Hoppe, Mol. Toxicol. 1987, 1, 525), la, lb, 2a and 2b products have very good compatibility with the skin. The L / D values are> 100. Therefore, the products are classified as non-irritating in this test.
Related application tests: Testing the skin care benefit and foam properties using a hand wash test [073] To assess the skin care benefit and foam properties of the la, lb, 2a product examples and 2b according to the invention, in aqueous, surfactant compositions (surfactant formulations), sensor hand washing tests were performed in comparison with the secondary cocamidopropyl betaine surfactant. Cocamidopropyl betaine is very widespread in the industry as
24/83 is a universal, gentle and secondary surfactant to promote foam and is a highly effective component in aqueous surfactant formulations.
[074] A group of 10 trained test persons washed their hands in a defined manner in this hand washing test and assessed foam properties and skin feel using a rating scale from 1 (bad) to 5 (very good) . The products were used in each case tested in a standardized surfactant formulation (Table 1).
[075] The surfactant formulation without the addition of a secondary surfactant was used as a control formulation 3. The surfactant formulations 6, 8 and 9 are the compositions according to the invention and the surfactant formulations 4, 5 and 7 are the compositions not according to the invention (Table 1).
Table 1: Test formulations for hand washing test according to (data in% by weight).
Formulation examples 3 4 5 6 7 8 9 Texapon® NSO(BASF Cognis, INCI: LaurethSodium sulphate, 28% resistance 32.1 32.1 32.1 32.1 32.1 32.1 32.1 TEGO® Betain F 50(Evonik Industries AG, INCI: Cocamidopropyl Betaine, 38% resistance)7.9Product example la:Soforolipideo (100% resistance) 3.0 Product example lb:90% Soforolipideo + 10% oleic acid 3.0 1.5 Product example 2a: Ramnolipideo(25% aqueous solution of resistance) 12.0
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Product example 2b:90% Ramnolipid + 10% oleic acid (25% aqueous resistance solution)12.0 6.0 NaCl 4.5 4.5 4.5 4.5 4.5 4.5 4.5 Citric acid, 30% ad pH 6.0 Demineralized water ad 100%
[076] Table 2 shows the results of the hand washing test.
Table 2: Results of the hand washing test
Test formulation 3 4 5 6 7 8 9 Foam behavior 2.2 3.1 3.0 3.0 3.4 3.3 3.3 Creamy foam 2.0 2.8 2.4 2.3 3.0 3.0 2.9 Sensation on the skin during washing 2.9 3.3 3.4 3, 6 3.4 3.5 3.5 ease ofrinsing 4.0 4.1 4.4 4.5 4.0 4.2 4.4 Skin smoothness after 3min 2.8 3.1 3.0 3.2 3.3 3, 6 3.5 Skin softness after 3min 3.0 3.1 3.0 3.2 3.4 3.5 3.4
[077] It is evident from the results of the measurements in Table 2 that the composition 6 according to the invention, using the product example lb (sorofolipid + 10% oleic acid) has a better skin feeling during washing with formulation and surprisingly easy rinse compared to comparison composition 4 according to the prior art, easy rinse is an increasingly important parameter in the development of new eco-friendly cosmetic products from saving water during lead washing to significantly better swings
26/83 ecological. In addition, it is evident that the composition 6 according to the invention was evaluated for better skin feel, skin smoothness and skin smoothness of test formulation 5 without oleic acid. Surprisingly, however, the foam establishments are hardly influenced here.
[078] Control formulation 3 has the poorest values across all properties. In addition, it is evident from the measurement values that composition 8, according to the invention, with product, for example 2b (ramnolipid + 10% oleic acid) and also formulation 9 with both examples of products (lb and 2b, 50:50) surprisingly leads to a clear improvement in foam properties and skin feel during washing and after application and drying compared to the prior art (formulation 4). Compared to Formulation 7 (ramnolipid without oleic acid), formulations 8 and 9 exhibited advantages specifically in the case of skin smoothness and, in the case of rinse.
[079] Contrary to expectations, in the present formulations, a certain fraction of free fatty acids in the biotensoactive exhibited no adverse effect on the foaming behavior or the thickening properties.
Other formulation examples:
[080] The formulation examples shown in the tables below show the exemplary representatives of a large number of possible compositions according to the invention.
27/83 [081]
The raw materials used are listed under the name INCI.
Unless otherwise stated, the data in the tables are given in% by weight. Use concentrations are given in% by weight of active substance.
[082]
If the preparation of the formulation requires separate preparation or mixing of the constituents of the formulation beforehand, this is called multiphase preparation.
If a two-phase preparation is required, the two phases are marked with and B in the established tables. In the case of three or four-phase processes, the phases are called A, B,
Systems based on lauryl ether sulfate:
Table 3: Conditioning of anti-dandruff shampoo
THE Glycol distearate 3.0% Sodium Laureth Sulfate 8.0% B perfume q. s . Silicone Quaternium-22 1.0% Ç Water ad 100% Acrylates / C10-30 Cross-linked alkyl acrylate polymer 0.2% Polyquaternium-10 0.3% NaOH, 25% 0.3% D Undecylenamidopropyl Betaine 2.5% Product example lb: Sophorolip + 10% oleic acid 2.5% Preservative q. s .
Table 4: Conditioning of anti-dandruff shampoo
THE Glycol distearate 3.0% Sodium Laureth Sulfate 10.0%
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B perfume q. s . Zinc pyrithione 1.0% Quaternium-80 0.5% Ç Water ad 100% Carbomer 0.5% Polyquaternium-10 0.3% NaOH, 25% 0.8% D Undecylenamidopropyl Betaine 3.0% Product example 2b: Ramnolipid + 10% oleic acid 2.0% Preservative q. s .
Table 5: Conditioning of dandruff shampoo
THE Glycol distearate 3.0% Sodium Laureth Sulfate 9.0% B perfume q. s . Climbazole 0.1% Quaternium-80 1.0% Ç Water ad 100% Acrylate crosslinked polymer / C10-30alkyl acrylate 0.3% Polyquaternium-10 0.2% NaOH, 25% 0.3% D Undecylenamidopropyl Betaine 3.5% Product example lb: Soforolipid + 10% oleic acid 1.5% Preservative q. s .
Table 6: Conditioning of anti-dandruff shampoo
THE PEG-3 distearate 2.5% Sodium Laureth Sulfate 10.0%
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B perfume q. s . Octopirox 0.3% Dimethicone 0.5% Ç Water ad 100% Acrylate crosslinked polymer / C10-30alkyl acrylate 0.2% Polyquaternium-10 0.3% NaOH, 25% 0.3% D Undecylenamidopropyl Betaine 2.0% Product example 2b: Ramnolipid + 10% oleic acid 3.0% Preservative, Dyes q. s .
Table 7: Hydrating skin cleansing
THE Sodium Laureth Sulfate 8.0% Product example lb: Soforolipid + 10% oleic acid 1.0% perfume q. s . B Water ad 200% Hydroxypropyl methylcellulose 1.2% Cocamidopropyl betaine 3.0% PPG-3 Miristil ether 1.0% Glycol distearate 2.0% PEG-200 Hydrogenated Glyceryl Palmate (e)PEG-7 Glyceryl cocoate 1.0% Preservative q. s . Citric acid Ad pH 5.5
Table 8: Hydration of the skin cleanser
THE Sodium Laureth Sulfate 7.0% Product example 2b: Ramnolipid + 10% 3.0%
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of oleic acid perfume q. s . B Water ad 100%Hydroxypropyl methylcellulose 1.2%Cocamidopropyl betaine 2.0%PPG-3 Miristil ether 1.0%PEG-3 Diestearate 1.0%PEG-200 Hydrogenated Glyceryl Palmate (e)PEG-7 Glyceryl cocoate 1.0%Preservative q. s .Citric acid ad pH 5.5
Table 9: Body cleaning product
THE Sodium Laureth Sulfate 8.5% Product example 2b: Soforolipid + 10% oleic acid 1.5% Bis-PEG / PPG-20/20 Dimethicone 0.3% perfume q. s . B Water ad 100% Hydroxypropyl methylcellulose 1.2% Citric acid monohydrate 2.5% Sodium cocoamfoacetate 2.0% PEG-3 Diestearate 2.0% PEG-200 Hydrogenated Glyceryl Palmate (e)PEG-7 Glyceryl cocoate 1.6% Preservative q. s . Citric acid ad pH 5.8
Table 10: Body cleaning product
THE Sodium Laureth Sulfate 8.0% Product example lb: Ramnolipid + 10% 1.2%
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of oleic acidBis-PEG / PPG-20/20 Dimethicone 0.3% perfume q. s . B Water ad 100% Hydroxypropyl methylcellulose 1.2% Citric acid monohydrate 0.5% Sodium cocoamfoacetate 3.0% Glycol Distearate (e) Laureth-4 (e)cocoamidopropyl betaine 2.0% PEG-200 Hydrogenated Glyceryl Palmate (e)PEG-7 Glyceryl cocoate 1.6% Preservative q. s . Citric acid ad pH 5.5
Table 11: Body cleaning foam
Sodium Laureth Sulfate 3.5% Product example 2b: Ramnolipid + 10% oleic acid 3.0% Sodium cocoamfoacetate 3.0% Water ad 100% Hydroxypropyl methylcellulose 0.5% Sodium lactate (e) Sodium PCA (e) Glycine(e) Fructose (e) Urea (e) Niacinamide (e (Inositol (e) Sodium benzoate (e) Lactic acid 1.0% Citric acid monohydrate ad pH 5.5 perfume q. s .
Table 12: Body cleaning foam
Sodium Laureth Sulfate 3.5% Product example lb: Soforolipid + 10% oleic acid 3.6% Product example 2b: Ramnolipid + 10% 0.7%
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oleic acid Sodium cocoamfoacetate 2.0 %% Water ad 100% Hydroxypropyl methylcellulose 0.5% Sodium lactate (e) Sodium PCA (e) Glycine 0.5% (e) Fructose (e) Urea (e) Niacinamide (e (Inositol (e) Sodium benzoate (e) Lactic acidPanthenol 0.2% Citric acid monohydrate ad pH 4.9 perfume q. s .
Table 13: Clear conditioning shampoo
Sodium Laureth Sulfate 9.0% Palmitamidopropyltrimonium chloride 1.0% PEG-200 Glyceryl Hydrogenated Palmate (e) PEG-7 Glyceryl cocoate 2.0% Product example 2b: Ramnolipideo + 10%oleic acid 0.7% Water ad 100% Creatine 1.0% Guar Hydroxypropyl ChlorideHydroxypropyltrimony 0.2% Cocamidopropyl Betaine 2.0% NaCl 0.5% perfume q. s . Preservative q. s .
Table 14: Clear conditioning shampoo
Sodium Laureth Sulfate 8.0% PEG-200 Glyceryl Hydrogenated Palmate (e) PEG-7 Glyceryl cocoate 2.0%
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Product example lb: Soforolipid + 10% oleic acid 1.5% Water ad 100% Polyquaternium-10 0.2% Cocamidopropyl Betaine 3.0% NaCl 0.3% perfume q. s . Preservative q. s .
Table 15: Misty conditioning shampoo
Sodium Laureth Sulfate 8.0% PEG-200 Glyceryl Hydrogenated Palmate (e) PEG-7 Glyceryl cocoate 2.0% Product example lb: Soforolipid + 10% oleic acid 1.5% Product example 2b: Ramnolipideo + 10%oleic acid 0.7% Water ad 100% Polyquaternium-10 0.2% Cocamidopropyl Betaine 1.5 %% Dimethicone (e) Dimethicone 1.0% Glycol diesterarate (e) Laureth-4 (e)Cocamidopropyl Betaine 2.0% NaCl 0.3% perfume q. s . Preservative q. s .
Table 16: Body cleaning product with pearlescent effect
Sodium Laureth Sulfate 9.0% Product example lb: Soforolipideo + 10% 2.5%
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oleic acidWater ad 100% Cocamidopropyl Betaine 1.5% Glycol diesterarate (e) Laureth-4 (e)Cocamidopropyl Betaine 2.0% PEG-18 Glycerol Oleate / Cocoate 1.5% NaCl 0.5% perfume q. s . Preservative q. s .
Table 17: Shower gel
Sodium Laureth Sulfate 4.0% Product example 2b: Ramnolipid + 10%oleic acid 2.5% Wheat protein glutamate hydrolyzed sodium cocoyl 1.5% PEG-5 disodium sulfosuccinate lauryl citrate(e) Capril / Capramidopropyl Betaine 2.5% Water ad 100% Cocamidopropyl Betaine 3.0% Capril / Capramidopropyl Betaine 1.0% Polyquaternium-7 0.5% PEG-200 Glyceryl Hydrogenated Palmate (e) PEG-7 Glyceryl cocoate 1.8% perfume q. s . Preservative q. s .
Table 18: Shower gel
Water ad 100% Sodium Laureth Sulfate 5.0% Product example lb: Soforolipid + 10% 2.5%
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oleic acid Wheat protein glutamate hydrolyzed sodium cocoyl 1.5% PEG-5 disodium sulfosuccinate lauryl citrate(e) Capril / Capramidopropyl Betaine 2.5% Cocamidopropyl Betaine 3.0% Capril / Capramidopropyl BetainePEG-200 Glyceryl Hydrogenated Palmate (e) PEG-7 Glyceryl cocoate 1.8% Preservative, perfume, dyes q. s .
Table 19: Shower gel
Water ad 100% Sodium Laureth Sulfate 9.0% Product example lb: Soforolipid + 10% oleic acid 4.0% Sodium cocoamfoacetate 1.5% Capril / Capramidopropyl Betaine 1.5% PEG-200 Hydrogenated glyceryl palmate (e)PEG-7Glycerol cocoate 0.5% Citric acid, 30% ad pH 6.1 Preservative, perfume q. s .
Table 20: Clear shower gel
Water ad 100% Sodium Laureth Sulfate 11.0% Product example 2b: Ramnolipid + 10%oleic acid 2.0% PEG-40 Hydrogenated castor oil 2.5% Cocoamidopropyl betaine 1.0% Sodium lactate (e) Sodium PCA (e) Glycine (e) Fructose (e) Urea (e) Niacinamide (e (
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Inositol (e) Sodium benzoate (e) Lactic acidPEG-18 glyceryl oleate / cocoate 2.0% Preservative, perfume q. s .
Table 21: Cleaning product for body and hair
Sodium Laureth Sulfate 7.0% Coconut betaine 3.0% Product example lb: Soforolipid + 10% oleic acid 1.5% Product example 2b: Ramnolipid + 10%oleic acid 1.5% Polyquaternium-10 0.2% PEG-150 distearate 1.5% Hydrogenated didecene 1.5% Water ad 100% Citric acid 2.0% Preservative, perfume, dyes q. s .
Table 22: Wash lotion for sensitive skin
Water ad 100% Sodium Laureth Sulfate 7.5% Cocoamidopropyl betaine 3.0% Glyceryl oleate 3.0% Product example lb: Soforolipid + 10% oleic acid 2.0% Sodium chloride 2.0% Glycol distearate 1.0% Sodium lactate 1.0% Cocoil disodium glutamate 1.0% Hydroxypropyltrimony starch chloride 0.5% Glyceryl stearate 0.4%
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Allantoin 0.1% Isopropyl Alcohol 0.1% Alcohol 0.1% Sorbitol 0.1% Urea 0.2% Serina 0.05% Tocopherol 0.05% Citric acid ad pH5.5 Preservative, perfume q. s .
Table 23: Dandruff shampoo
Water ad 100% Sodium Laureth Sulfate 7.0% Sodium lauryl sulfate 4.0% Product example lb: Soforolipid + 10%oleic acid 3.0% Cocamide MEA 2.5% Zinc carbonate 1.0% Glycol distearate 1.0% Sodium chloride 1.0% Zinc pyrithione 1.0% Dimethicone 1.0% Cetyl alcohol 0.5% Polyquartenium-10 0.2% Sodium Xylenesulfonate 0.2% Ammonium Laureth Sulphate 0.2% Diethylenetriamine sodium-phosphonatepentamethylene 0.1% Ethidronic acid 0.1%
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Hydantoin DMDM 0.1% Disodium EDTA 0.1% Trisodium EDTA 0.05% Preservative, perfume, dyes q. s .
Table 24: Shampoo
Water ad 100% Sodium Laureth Sulfate 5.0% Product example 2b: Ramnolipid + 10%oleic acid 4.0% Cocamidopropyl betaine 2.0% Sodium chloride 2.0% PEG-3 distearate 1.5% Polyquaternium-10 0.3% Citrus aurantifolia fruit juice 0.2% Paullinia cupana extract 0.2% PEG-40 hydrogenated castor oil 0.2% Propylene glycol 0.2% Glycerin 0.2% Citric acid ad pH5.0 Preservative, perfume q. s .
Table 25: Shampoo
Water ad 100% Sodium Laureth Sulfate 7.0% Cocamidopropyl betaine 2.5% Product example lb: Soforolipid + 10%oleic acid 1.5% Sodium chloride 1.5% Glycol distearate 1.0%
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Guar hydroxypropyl chloridehydroxypropyltrimony 0.3% Propylene glycol 0.3% Panthenol 0.3% Dimethicone propyl PG-betaine 0.3% Glyoxylic acid 0.02% Coumarina 0.01% Citric acid ad pH5.5 Preservative, perfume q. s .
Table 26: Shampoo
Water ad 100% Sodium Laureth Sulfate 5.0% TEA-Cocoil glutamate 3.0% Glycerin 3.0% Product example lb: Ramnolipid + 10%oleic acid 2.0% Sodium chloride 2.0% Coconut betaine 1.0% Cocamide MIPA 0.5% Glycol distearate 0.5% Methyl cocoyl sodium taurate 0.4% Sodium PCA 0.2% Hexylene glycol 0.1% Polyquaternium-10 0.1% Disodium cocoamfodiacetate 0.2% Ceteareth-60 myristyl glycol 0.2% Brassica campestre seed oil (seed) 0.1% Citric acid ad pH
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5.5 Preservative, perfume q.s.
Table 27: Shampoo
Water ad 100% Sodium Laureth Sulfate 5.0% Product example lb: Soforolipideo + 10%oleic acid 3.5% Sodium Laureth-4 Carboxylate 1.5% Dipropylene glycol 1.5% Sodium cocoamfoacetate 1.0% Glycol distearate 0.8% Lauramide MIPA 0.5% Hydroxyethyl sarcosine of C12-14 hydroxyalkyl 0.5% Dimethicone 0.4% Polyquaternium-10 0.2% Polyquaternium-7 0.1% Sodium citrate 0.1% Hydrolyzed collagen 0.1% Laureth-25 0.1% Canine fruit fruit oil 0.1% Disodium EDTA 0.1% Citric acid ad pH5.5 Preservative, perfume q.s.
Table 28: Shower gel
Water ad 100% Product example lb: Soforolipideo + 10%oleic acid 4.2% Sodium Laureth Sulfate 4.0%
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Cocoamidopropyl betaine 2.5% Glycerin 2.0% Sodium chloride 1.5% Miristoil sodium sarcosinate 1.2% Prunus cerasus juice 0.7% Caramel 0.2% Disodium EDTA 0.1% Propylene glycol 0.2% PEG-120 methyl glucose trioleate 0.3% Citric acid ad pH5.5 Preservative, perfume q. s .
Table 29: Shower gel
Water ad 100% Ammonium Laureth Sulphate 5.5% Cocoamidopropyl betaine 2.5% Product example lb: Soforolipid + 10%oleic acid 1.5% Sorbitol 1.2% Methyl MEA cocamide 0.7% PEG-7 glyceryl cocoate 0.6% Cocoil sodium alaninate 0.8% Sodium chloride 0.7% Disodium EDTA 0.1% Hydantoin DMDM 0.1% Santalum extract album (extract) 0.1% Lactic acid ad pH5.5 Preservative, perfume q. s .
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Table 30: Hand cleaning paste
Water ad 100% Laureth-5 5.0% Juglans Regia 3.0% Sodium Laureth Sulfate 5.0% Product example lb: Soforolipideo + 10%oleic acid 2.0% Bentonite 1.0% Sodium cocoamfoacetate 0.7% Oleic acid 0.5% C12-13 alkyl lactate 0.5% Aloe Barbadensis 0.3% Sodium chloride 0.3% PEG-14MÍO 0.2% Lactic acid ad pH6, 0 Preservative, perfume q. s .
Table 31: Bath oil
Glycerin soybean oil 40.0% Lecithin 20.0% MIPA-Laureth sulfate 4.0% Product example lb: Soforolipideo + 10%oleic acid 4.0% Laureth-4 3.0% Cocamide DEA 1.0% Poloxamer 101 1.0% Persea Gartissima Oil 1.0% Sodium lactate 0.5% Water ad 100%
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Caprylic triglyceride / capric 0.7% Ascorbyl palmitate 0.5% Sodium citrate 0.5% Preservative, perfume q. s .
Alkyl sulfate based systems:
Table 32: Care in the shower
Water ad 100% Ammonium Lauryl Sulfate 5.0% Glycoside Lauryl 3.0% Cocamidopropyl betaine 2.5% Product example lb: Soforolipid + 10%oleic acid 2.0% Lauroil sarcosina 0.7% Bambusa arundinacea extract 1.0% Citrus grandis extract 1.0% Alcohol 0.7% Guar hydroxypropyl chloridehydroxypropyltromonium 0.3% Citrus medica limonum oil 0.3% Preservative, perfume q. s .
Table 33: Baby wash lotion and shampoo
Water ad 100% Coconut sodium sulfate 5.5% Glycerin 3.5% Product example lb: Soforolipid + 10%oleic acid 3.0% Decyl glycoside 1.5% Alcohol 1.0% Xanthan gum 1.0%
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Bellis Perennis Extract 0.7% Arnica Montana Extract 0.7% Chamomilla Recutita Extract 0.5% Cocoil disodium glutamate 0.5% Cocoil sodium glutamate 0.3% Preservative, perfume q. s .
Table 34: Shampoo
Water ad 100% Ammonium Lauryl Sulfate 3.0% Ammonium Laureth Sulphate 2.5% Cocamidopropyl betaine 2.0% Product example 2b: Ramnolipid + 10%oleic acid 1.5% Sodium cocoyl isethionate 1.0% Ammonium chloride 0.8% Methyl cocoyl sodium taurate 0.7% Sodium lauroamfoacetate 0.5% Glycol distearate 0.5% Laureth-7 0.4% Propylene glycol 0.4% Hydroxypropyltrimony guar chloride 0.2% Dipropylene glycol 0.2% EDTA tetrasodium 0.1% Sodium Xylene Sulphonate 0.1% PEG-20 Castor Oil 0.2% Sodium cocoamfoacetate 0.2% Quatermíum-80 0.3% Amazing Persea Oil 0.3% Citric acid, 30% ad pH
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5.5 Preservative, perfume q. s .
Betaine-based systems
Table 35: Gentle, sulfate-free body and hair cleanser
Cocamidopropyl betaine 5.0% Sodium cocoamfoacetate 4.0% Product example 2b: Ramnolipid + 10%oleic acid 1.5% Sucrose cocoate 1.5% PEG-120 Glucose methyl dioleate 2.0% Polyquaternium-10 0.2% Water ad 100% Citric acid, 30% ad pH6, 6 Preservative, perfume, dyes q. s .
Table 36: Body cleanser and hair free of
PEG, smooth
Water ad 100% Cocamidopropyl betaine 5.5% Glycoside Lauryl 3.0% Sodium cocoamfoacetate 3.0% Product example lb: Soforolipid + 10%oleic acid 1.5% Hydroxypropyl methylcellulose 0.5% Isoesteramide MIPA (e) glyceryl laurate 1.4% Polyquaternium-7 0.5% Citric acid, 30% ad pH5.0
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Preservative, perfume q. s .
Table 37: Shower care for sensitive skin
Water ad 100% Cocamidopropyl betaine 5.0% Myreth sodium sulfate 3.0% Sodium Laureth Sulfate 1.5% Product example lb: Soforolipid + 10%oleic acid 1.5% PEG-7 glyceryl cocoate 1.5% Glycerin 1.0% Glyceryl glycoside 1.0% Bisabolol 0.3% Recipe Chamamilla flower extract 0.3% Sodium chloride 0.3% PEG-40 hydrogenated castor oil 0.3% Polyquaternium-7 0.3% PEG-90 glyceryl isostearate 0.3% PEG-200 hydrogenated glyceryl palmate 0.3% Benzophenone-4 0.1% Laureth-2 0.1% Citric acid ad pH4.9 Preservative, perfume q. s .
Table 38: Baby shampoo
Water ad 100% Cocamidopropyl betaine 6.0% PEG-80 Sorbitan Laurate 3.0% Product example 2b: Ramnolipid + 10%oleic acid 2.0%
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Trideceth sodium sulfate 1.5% PEG-150 distearate 1.5% EDTA tetrasodium 0.5% Polyquaternium-10 0.2% Quaternium-15 0.2% Sodium hydroxide 0.3% Citric acid ad pH5.9 Preservative, perfume, dyes q. s .
Table 39: Baby shampoo
Water ad 100% Cocamidopropyl betaine 7.0% Product example lb: Soforolipid + 10%oleic acid 2.5% Sodium Laureth Sulfate 1.5% PEG-120 glucose methyl dioleate 1.0% Coconut glycoside 1.0% Glyceryl oleate 0.7% Quaternium-22 0.3% C12-15 alkyl lactate 0.2% Quaternium-2 8 0.2% Citric acid ad pH5.5 Preservative, perfume, dyes q. s .
Table 40: Baby shampoo
Water ad 100% PEG-80 Sorbitan Laurate 3.5% Cocamidopropyl betaine 3.5% Trideceth sodium sulfate 3.5%
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Glycerin 1.0% Product example lb: Soforolipideo + 10%oleic acid 0.9% Lauroamfoglicinato 0.7% PEG-150 distearate 0.5% Sodium Laureth-13 Carboxylate 0.5% Amygdalus Dulcis Sodium Extract 0.3% Polyquaternium-10 0.2% EDTA tetrasodium 0.1% Quaternium-15 0.1% Citric acid ad pH5.2 Preservative, perfume, dyes q. s .
Table 41: Shampoo
Water ad 100% Cocamidopropyl betaine 4.0% Sodium lauryl sulfatoacetate 3.0% Product example lb: Soforolipideo + 10%oleic acid 2.0% Disodium Laureth Sulfosuccinate 1.0% Sodium lauroyl sarcosinate 1.0% Glycol distearate 0.9% Sodium chloride 0.9% Decyl glycoside 0.5% Polyquaternium-10 0.3% PPG-5-Ceteth-20 0.5% Coconut betaine 0.5% PEG-55 propylene glycol oleate 0.4% Propylene glycol 0.3%
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Salicylic acid 0.2% Carbomer 0.3% Sodium hydroxide 0.2% Citric acid ad pH5.5 Preservative, perfume, dyes q. s .
Amfoacetate-based systems:
Table 42: Body cleaning product, free of sulfate and
PEG
Water ad 100% Sodium cocoamfoacetate 5.0% Disodium Lauryl Sulfosuccinate 1.2% Product example lb: Soforolipideo + 10%oleic acid 2.5% Cocamidopropyl betaine 3.0% Cocamidopropyl betaine (e) glyceryl laurate 1.0% Citric acid ad pH5.0 Preservative, perfume q. s .
Table 43: Shampoo, free of sulfate and PEG
Water ad 100% Sodium cocoamfoacetate 5.5% Cocoil disodium glutamate 2.0% Product example 2b: Ramnolipid + 10%oleic acid 2.0% Polyquaternium-10 0.2% Palmitamidopropyltrimonium chloride 1.0% Isoesteraramide MIPA 1.0% Citric acid ad pH
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5.5 Preservative, perfume q. s .
Table 44: Body and hair cleanser, free of sulfate and PEG
Sodium cocoamfoacetate 3.5% Product example 2b: Ramnolipideo + 10%oleic acid 3.5% Disodium Lauryl Sulfosuccinate 1.5% Sorbitan Sesquicaprilat 0.9% Water ad 100% Cocoamidopropyl betaine 3.0% Citric acid, 30% ad pH5.5 Preservative, perfume q. s .
Table 45: Gentle cleansing gel, free of sulfate and PEG, according to Ecocert
Water ad 100% Xanthan gum 1.5% Sodium cocoamfoacetate 3.0% Product example lb: Soforolipid + 10%oleic acid 2.5% Cocamidopropyl betaine 2.0% Capril / capramidopropyl betaine 2.0% Sucrose cocoate 0.6% Polyglyceryl caprate-3 3.0% Cocamidopropyl betaine (e) glyceryl laurate 1.3% NaCl 1.5% Citric acid, 30% ad pH5.0
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Preservative, perfume, dyes q. s .
Table 46: Body cleaning product
Water ad 100% Glycerin 5.0% Hybrid oil from Helianthus Annuus 3.5% Cocamidopropyl betaine 3.5% Sodium hydroxypropyl phosphate starch 3.0% Sodium Laureth Sulfate 3.0% Sodium cocoyl glycinate 2.5% Product example 2b: Ramnolipid + 10%oleic acid 2.5% Lauric acid 1.0% Sodium lauroyl isethionate 1.0% Stearic acid 0.5% Sodium palmitate 0.5% Sodium chloride 0.5% Hydroxypropyltrimony guar chloride 0.2% Sodium stearate 0.2% EDTA tetrasodium 0.1% Tetrasodium etidronate 0.1% Alumina 0.1% Citric acid, 30% ad pH5.5 Preservative, perfume, dyes q. s .
APG-based systems:
Table 47: Gentle body and hair cleanser
Water ad 100% Glycoside Lauryl 5.0% Coconut glycoside 2.0%
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Product example 2b: oleic acid Ramnolipid + 10% 3.0% Sucrose cocoate1.5% Cocamidopropyl betaine4.0% Carbomer1.0% Citric acid, 30%ad pH5.5 Preservative, perfume, dyes q.s.
Table 48: Pampering for shower
Water ad 100% Sesamum indicum seed oil (sesame) 5.0% Coconut glycoside 5.0% Alcohol 5.0% Product example 2b: Ramnolipid + 10%oleic acid 3.0% Cocoil disodium glutamate 3.0% Glycerin 2.5% Rosehip seed oil 0.5% Xanthan gome 0.7% Lactic acid, 90% ad pH5.5 perfume q.s.
Table 49: Shower and shower gel
Water ad 100% Glycerin 6.0% Coconut glycoside 5.5% Caprylil / capryl glycoside 5.0% Product example lb: Soforolipideo + 10%oleic acid 2.0%
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Coconut sodium sulfate 3.5% Prunus armenica fruit extract (apricot) 2.0% Xanthan gome 2.0% Alcohol 1.0% perfume q. s .
Table 50: Shower gel
Water ad 100% Coconut glycoside 7.0% Coconut sodium sulfate 4.0% Lauryl glycoside 2.0% Product example lb: Soforolipideo + 10%oleic acid 2.0% Glyceryl oleate 2.0% Glycerin 2.0% Inulin 0.5% Aloe barbadensis leaf juice 0.4% Sorbitol 0.4% Betaine 0.2% Cocoil sodium glutamate 0.2% Cocoil disodium glutamate 0.2% Cocos Nucifera fruit extract (coconut) 0.1% Maris salt 0.1% Glyceryl caprylate 0.1% Sodium PCA 0.1% PCA of cocoyl ethyl arginate 0.1% Potassium sorbate 0.9% Citric acid ad pH5.5 perfume q. s .
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Table 51: Bath foam for children
Water ad 100% Product example lb: Soforolipid + 10% 4.0% oleic acid Lauryl glycoside 4.0% Aloe Barbadensis leaf extract 4.0% Sodium Lauryl Sulfoacetate 2.0% Glycerin 2.0% Polyglyceryl Laurate-10 2.0% Coconut glycoside 2.0% Glyceryl oleate 0.5% Cocoil disodium glutamate 0.4% Cocoil sodium glutamate 0.4% Calendula Officinalis fruit extract 0.2% Sodium chloride 0.2% Citric acid ad pH5.5 perfume q. s .
Table 52: Shower gel
Water ad 100% Product example 2b: Ramnolipideo + 10%oleic acid 4.0% Coconut glycoside 4.0% Glycerin 4.0% Cocoil disodium glutamate 3.0% Cocoil sodium glutamate 2.0% Polyglyceryl Laurate-10 1.0% Glyceryl caprylate 1.0% Rubus Idaeus fruit extract (raspberry) 0.3%
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Sodium PVA 0.2% Xanthan gum 0.6% Glyceryl oleate 0.3% Phytic acid 0.1% Citric acid ad pH5.5 perfume q. s .
Table 53: Ultra-sensitive bath cream
Water ad 100% Coconut glycoside 7.0% Alcohol 3.0% Product example lb: Soforolipid + 10%oleic acid 3.0% Glycerin 2.5% Simmondsis Chinensis seed oil 1.5% Xanthan gum 1.3% Cocoil disodium glutamate 1.0% Glyceryl oleate 0.8% Cocoil sodium glutamate 0.5% Citric acid ad pH5.5 perfume q. s .
Table 54: Dandruff shampoo
Water ad 100% Sorbitol 5.5% Glycerin 5.0% Coconut glycoside 4.5% Product example lb: Soforolipid + 10%oleic acid 3.5%
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Loess 1.0% Zea Mays oil 1.0% Sodium lauroyl lactylate 1.5% Cocoil sodium glutamate 1.0% Cocoil disodium glutamate 1.0% Xanthan gum 0.7% Kaolin 0.3% Canola oil 0.3% Coco-glycoside sodium tartrate 0.2% Tocopherol 0.1% Citric acid ad pH5.3 perfume q. s .
Table 55: ECOCERT ingredients, mild body and hair cleanser
Lauryl glycoside 3.0% Product example lb: Soforolipid + 10%oleic acid 2.0% Cocamidopropyl betaine (e) glyceryl laurate 5.0% Sorbitan Sesquicaprilat 0.9% Water ad 100% Cocamidopropyl betapine 4.0% Citric acid, 30% ad pH5.5 Preservative, perfume q. s .
Table 56: Gentle cleaning foam
Water ad 100% Glycine soy oil 8.0% Glycerin 5.0%
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Alcohol 5.0% Product example 2b: Ramnolipideo + 10%oleic acid 4.0% Coconut glycoside 3.5% Caprylic / capric triglyceride 2.0% Coconut sodium sulfate 2.0% Sodium lactate 1.0% Cocoil sodium glutamate 1.0% Cocoil disodium glutamate 0.6% Argania Spinosa seed oil 0.6% perfume q. s .
Table 57: Washing gel
Water ad 100% Alcohol 7.0% Glycerin 5.5% Coconut glycoside 4.0% Product example lb: Soforolipid + 10%oleic acid 3.0% Cocoil sodium glutamate 2.0% Xanthan gum 2.0% Equisetum Arvense leaf extract 1.0% Cocoil disodium glutamate 0.4% Citric acid ad pH5.5 Preservative, perfume q. s .
Table 58: Gentle body and hair cleanser, free of sulfate and PEG
Lauryl glycoside 3.5% Product example lb: Soforolipid + 10% 2.0%
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oleic acid MIPA isostearamide (e) glycerol laurate 1.0% Water ad 100% Coconut glycoside 1.0% Sodium cocoamfoacetate 3.0% Cocoamidopropyl betaine 3.5% Citric acid, 30% ad pH5.5 Preservative, perfume q. s .
Table 59: Wet wipes
Water ad 100% Caprylic acid / caprylic glycoside 3.0% Product example 2b: Ramnolipid + 10%oleic acid 3.5% Coconut glycoside 2.5% Polyaminopropyl biguanide 1.0% Propylene glycol 1.0% Simethicone 0.5% Aloe Barbadensis Extract 0.3% Citric acid ad pH5.7 Preservative, perfume q. s .
Table 60: Bio bath for showers
Water ad 100% Glycerin 5.5% Lauryl glycoside 4.0% Product example 2b: Ramnolipid + 10%oleic acid 3.0% Ammonium Lauryl Sulfate
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Cocoamidopropyl betaine 2.0% Sarcosine of lauroíla 2.0% Guar hydroxypropyl chloridehydroxypropyltrimony 1.0% Alcohol ad pH5.5 Preservative, perfume, dyes q. s .
Table 61: Baby shampoo
Water ad 100% Coconut glycoside 4.5% Sodium lauroamfoacetate 3.5% Sodium Laureth Sulfate 2.5% Product example lb: Soforolipid + 10%oleic acid 2.5% Citric acid ad pH5.5 Polysorbate 20 0.7% PEG-80 sorbitan laurate 0.5% PEG-150 distearate 0.3% Polyquaternium -10 0.3% Butylene glycol 0.2% Propylene glycol 0.2% Lactic acid 0.2% Glucose 0.1% Preservative, perfume, dyes q. s .
Table 62: Gentle body cleansing product
Water ad 100% Lauryl glycoside 3.5% Sorbitan Sesquicaprilat 0.6%
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Coconut glycoside 0.5% Product example 2b: Ramnolipid + 10%oleic acid 1.5% Disodium Lauryl Sulfosuccinate 2.0% Cocamidopropyl betaine 3.5% Citric acid, 30% 1.5% Preservative, perfume q.s.
Table 63: Shower gel
Water ad 100% Lauryl glycoside 8.0% Cocamidopropyl betaine 2.5% Product example lb: Soforolipideo + 10%oleic acid 2.5% Dimethicone propyl PG-betaine 0.3% PEG-7 glyceryl cocoate 2.0% PEG-18 glyceryl oleate / cocoate 2.0% Preservative, perfume q.s.
Table 64: Gentle body cleansing product, in compliance with Ecocert, free of betaine, sulfate and PEG
Water ad 100% Lauryl glycoside 4.0% Product example 2b: Ramnolipid + 10%oleic acid 0.9% Sorbitan Sesquicaprilat 0.6% Coconut glycoside, Cognis 1.0% Cocoil sodium / disodium glutamate 2.0% Sodium cocoamfoacetate 3.0% Citric acid ad pH5.1
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Preservative, perfume q. s .
Sulphonate-based systems
Table 65: Sulfate-free shampoo with MHEC
Water ad 100% C14-16 Sodium Olefin Sulfonate 4.0% Product example 2b: Ramnolipideo + 10%oleic acid 3.0% Cocamidopropyl betaine 3.0% Methylhydroxyethylcellulose 1.5% Preservative, perfume q. s .
Table 66: Acne cleansing oil-free product
Water ad 100% C14-16 sodium olefin sulfonate 4.0% Cocamidopropyl betaine 3.0% Product example lb: Soforolipideo + 10%oleic acid 2.5% C12-15 Pareth-15 sodium sulfonate 2.5% Aloe Extract 1.0% Chamomile extract 1.0% PG-dimonium linoleamidopropyl phosphate chloride 0.7% Disodium EDTA 0.2% Propylene glycol 0.3% Salicylic acid 2.0% Sodium chloride 1.0% Preservative, perfume q. s .
Table 67: Wash emulsion for sensitive and problematic skin
Water ad 100% C14-16 sodium olefin sulfonate 4.0%
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Sodium Laureth Sulfate 3.0% Product example lb: Soforolipideo + 10%oleic acid 2.0% Disodium Laureth Sulfosuccinate 1.5% Sodium chloride 2.0% Laureth-2 1.0% Panthenol 0.5% Glycol distearate 0.5% Saccharide isomerates 0.2% Allantoin 0.2% Niacinamide 0.1% Pyridoxine HC1 0.1% Glycine 0.1% Alanine 0.1% Lysine 0.1% Biotin 0.1% Glycerin 0.5% Sodium lauroyl glutamate 0.5% Sodium citrate 0.5% Cocamidopropyl betaine 0.5% Sorbitan laurate 0.4% Peg-120 Methyl glucose dioleate 0.3% Preservative, perfume q. s .
Sulfosuccinate-based systems
Table 68: Children's gel and shampoo
Water ad 100% Disodium Laureth Sulfosuccionate 4.5% Product example 2b: Ramnolipid + 10%oleic acid 3.5%
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Cocamidopropyl hydroxysultaine 2.5% Cocamidopropyl betaine 1.5% Decyl glycoside 1.0% PEG-18 glyceryl oleate / cocoate 0.7% Laureth-2 0.5% Sodium chloride 0.5% Panthenol 0.2% Niacinamide 0.1% Pyridoxane hydrochloride 0.1% Polyquatermium-10 0.3% Glycerin 0.3% Inulin 0.1% Citric acid ad pH5.7 Preservative, perfume, dyes q. s .
Table 69: Soft baby shampoo
Water ad 100% Disodium Laureth Sulfosuccionate 3.5% Product example lb: Soforolipideo + 10%oleic acid 3.5% MIPA isostearamide (e) glycerol laurate 1.7% PEG-7 glyceryl cocoate 0.5% Sodium cocoamfoacetate 3.0% Palmitamidopropyltrimonium chloride 2.3% Citric acid, 30% ad pH6, 0 Preservative, perfume, dyes q. s .
Table 70: Gentle face cleaning foam
Water ad 100%
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PEG-5 disodium sulfosuccinate lauryl citrate(e) Capril / capramidopropyl betaine 5.5% Product example lb: Soforolipideo + 10%oleic acid 3.0% Capril / capramidopropyl betaine 2.0% Polyglyceryl-3 caprate 0.5% Creatine 0.2% Hydroxypropyl methylcellulose 0.5% Sodium lactate (e) PCA sodium (e) glycine(e) fructose (e) urea (e) niacinamide (e)inositol (e) sodium benzoate (e) lactic acid 1.0% Preservative, perfume q. s .
Sarcosinate-based systems
Table 71: Shampoo
Water ad 100% Sodium lauroyl sarcosinate 5.0% Coconut betaine 3.0% Product example 2b: Ramnolipideo + 10%oleic acid 1.5% Cocamide DEA 4.5% Cetrimonium chloride 0.3% Steronium Chloride 0.1% Disodium EDTA 0.2% Citric acid ad pH6.7 Preservative, perfume q. s .
Table 72: Shampoo
Water ad 100% Sodium lauroyl sarcosinate 5.0%
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Product example lb: Soforolipid + 10%oleic acid 2.5% Cocamidopropyl betaine 4.0% Palmitamidopropyltrimonium chloride 0.5% Polyquaternium-10 0.1% Citric acid ad pH5.1 Preservative, perfume q. s .
Table 73: Shampoo
Water ad 100% Sodium lauroyl sarcosinate 3.5% Product example lb: Soforolipid + 10%oleic acid 3.5% Sodium cocoamfoacetate 2.5% Cocamidopropyl betaine 1.0% Coconut betaine 1.0% Coco-glycoside 0.5% Glyceryl oleate 0.5% Polyquaternium-7 0.3% Polysorbate 20 0.2% Silicone quaternium-22 0.3% PEG-120 methyl glucose dioleate 0.3% Hibuscis Sabdariff (Hibiscus) Extract 0.1% Glycerin 0.2% Sodium hydroxymethylglycinate 0.2% Citric acid ad pH5.1 Preservative, perfume q. s .
Table 74: Gentle body cleanser
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Water ad 100% Sodium lauroyl sarcosinate 2.5% Sodium lauroamfoacetate 2.5% Cocoil sodium alaninate 2.0% Product example 2b: Ramnolipid + 10%oleic acid 1.5% Sodium cocoamfoacetate 1.5% Lauryl glycoside 1.5% Cocoil disodium glutamate 0.5% Sodium Lauryl Glucose Carboxylate 0.5% PEG-150 distearate 0.5% Polysorbate 20 0.4% Glycerin 0.5% Seaweed extract 0.1% Methyl gluceth-20 0.2% Coco-glycoside 0.3% Glyceryl oleate 0.5% Allantoin 0.2% PEG-40 hydrogenated castor oil 0.4% Disodium EDTA 0.1% Citric acid ad pH5.5 Preservative, perfume q. s .
Systems based on others (sultaine, anisate, isethionate, glutamate, glycinate):
Table 75: Baby care bath
Water ad 100% Sorbitol 3.5% Cocamidopropyl hydroxysultaine 3.5%
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Product example lb: Soforolipid + 10%oleic acid 3.0% Cocamidopropyl betaine 2.5% Lauryl glycoside 1.0% Coco-glycoside 1.0% Sodium chloride 1.5% Glyceryl oleate 0.9% Amygdalus Dulcis Sodium Extract 0.3% Sodium carboxymethyl betaglucane 0.3% Glycerin 0.3% Styrene / acrylates copolymer 0.3% Inulin 0.1% Preservative, perfume, dyes q. s .
Table 76: Wet cleaning wipes
Water ad 100% Glycerin 5.0% Sodium anisate 3.5% Sodium levulinate 3.5% Product example lb: Soforolipid + 10%oleic acid 3.0% Glyceryl caprylate 1.0% Tocopheryl acetate 0.5% Sodium citrate 0.5% Xanthan gum 0.5% Hydrolyzed milk protein 0.4% Prunus Armeniaca seed oil 0.3% Magnesium stearate 0.2% Preservative, perfume q. s .
Table 77: Shower gel
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Water ad 100% Sodium lauroyl methyl isethionate 4.5% Product example lb: Soforolipid + 10%oleic acid 3.0% Cocamidopropyl betaine 2.5% Sodium chloride 2.5% Glycerin 1.5% Polyglyceryl-4 caprate 0.6% Sucrose cocoate 0.5% Ethylenediamine trisodium disuccinate 0.2% Zinc laurate 0.1% Salicylic acid 0.1% Propylene glycol 0.1% Aloe Barbadensis leaf juice 0.1% Sodium hydroxide 0.1% Tocopherol 0.1% Citric acid ad pH5.5 Preservative, perfume q. s .
Table 78: Shampoo
Water ad 100% Sodium cocoyl isethionate 3.0% Product example 2b: Ramnolipid + 10%oleic acid 3.0% Cocamidopropyl hydroxysultaine 3.0% Cocamide DEA 2.5% Sodium lauroyl methyl isethionate 2.0% Inulin 1.0% Cocoil sodium glutamate 0.7%
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Sodium lauroyl glutamate 0.7% Hydrolyzed wheat protein 0.4% Guar hydroxypropyl chloridehydroxypropyltrimony 0.1% Polyquaternium-10 0.1% Arnica Montana flower extract 0.1% Styrene / acrylates copolymer 0.2% Disodium EDTA 0.1% Sodium hydroxide 0.1% Lactic acid, 90% ad pH5.5 Preservative, perfume q. s .
Table 79: Baby cleaner
Water ad 100% Glycerin 5.0% Product example lb: Soforolipid + 10%oleic acid 3.0% Pentylene glycol 1.0% Sodium cocoamfoacetate 0.5% Cocamidopropyl betaine 0.5% Helianthus Annuus seed oil 0.5% Lauryl glycoside 0.4% PEG-7 Sodium olive oil carboxylate 0.3% Hydroxyethylcellulose 0.2% Cocoil sodium glutamateSodium Lauryl Glucose CarboxylateSodium amfoacetate cocoa butterPreservative, perfume q. s .
Table 80: Hair and body cleansing foam
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Water ad 100% Cocoil sodium glutamate 5.0% Glycerin 3.0% Sodium Laureth Sulfate 3.0% Product example 2b: Ramnolipid + 10%oleic acid 2.0% Pentylene glycol 2.0% Cocoil sodium alaninate 1.0% PEG-200 Hydrogenated glyceryl palmate (e)PEG-7 Glyceryl cocoate 1.2% PEG-60 Glyceryl isostearate 0.5% PG-dimonium cocamidopropyl chloride phosphate 0.3% Butylene glycol 0.3% Propylene glycol 0.5% Ginkgo Biloba leaf extract 0.1% Tetrasodium EDTA 0.1% Benzophenone-4 0.2% Lactic acid, 90% ad pH5.3 Preservative, perfume, dyes q. s .
Table 81: Makeup remover
Water ad 100% PEG-8 5.0% Isopentyldiol 2.0% PEG-20 glyceryl triiso stearate 2.0% Glycerin 2.0% Hydrogenated polyisobutene 2.0% Potassium cocoyl glycinate 2.0% Lauryl hydroxysultaine 2.0%
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Product example lb: Soforolipideo + 10%oleic acid 2.0% Butylene glycol laurate 1.5% Lauryl glycoside 1.5% Alcohol 0.5% Disodium EDTA 0.1% Citric acid ad pH5.5 Preservative, perfume, dyes q. s .
Table 82: Foam of body cleaning product
Water ad 100% Sodium cocoyl glycinate 6.0% Product example 2b: Ramnolipid + 10%oleic acid 4.0% Coconut betaine 2.0% Glycerin 1.0% Sodium chloride 1.0% Acrylate crosslinked polymer / C10-3- alkyl acrylate 0.5% Sodium hydroxide 0.4% PEG-14M 0.3% Salicylic acid 0.1% Polyquaternium-10 0.1% Glycol distearate 0.2% Citric acid ad pH5.5 Preservative, perfume, dyes q. s .
Table 83: Examples of additional formulation
I II III IV V SAW VII VIII IX X
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Water ad 100% Product example lb: Soforolipid + 10% oleic acid 10.0%3.0% 3.5%2.0%4.0%3.0% Product example2b: Ramnolipid +10% oleic acid12.0% 5.5%7.0% 2.0% 5.5%3.5%Laureth sulfatesodium - - - 7.0% - - - 4.5% - - Lauryl sulfatesodium - - - - 5.0% - - - 3.5% - Cocamidopropyl betaine - - - - - 6.0% - 2.5% - 4.5% Cocoamfoacetatesodium - - - - - - - - 3.5% - Cocoglycoside - - - - - - 5.5% - - 2.5% Sucrose cocoate 0.5% 1.0% 1.0% 1.0% 1.0% 0.5% 1.0% 1.0% 1.0% 1.0% Hydroxypropyl methylcellulose 0.5% - - - - 0.3% - - - 0.1% Caprate ofPolyglyceril-4 - - 1.0% - - - - - - - Hydroxypropyl guar hydroxypropyltrimony chloride 0.2% 0.2% 0.2% 0.2% 0.2% 0.2% 0.2% 0.2% 0.2% 0.2% Silicone Quaternium-22 - - - 0.5% 0.5% - - - - - Amodimethicone - - - - - - 0.5% - - - Glycol distearate - - 0.5% - 0.5% - - - 0.5% 0.5% Carbomer 1.0% - - - 0.5% - - - 0.5% -
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Sodium hydroxide,25% 1.5% - - - 0.8% - - - 0.7% - Isoestereamide MIPA; - 1.5% - - - - - - 1.0% 0.5% Glyceryl laurate Sesquicaprilat - 0.5% - 0.5% 0.5% 1.2% 1.0% - - 1.3% sorbitan Sodium chloride 1.0% 1.0% - 0.5% - 1.5% - 2.0% 1.5% - Peg-200 Palmato de - - - 0.4% - - - 0, 6 - - glycerol hydrogenated; PEG07 glyceryl cocoate Xanthan gum - - 1.2% - - - 1.0% - - 0.5% Panthenol 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% Citric acid ad pH 5.5 Preservative, perfume, q.sdyes
Table 84: Examples of additional formulation
XI XII XIIIII XIV XV XVI XVII XVIII XIX XX Water ad 100% Product example lb: Soforolipid + 10% oleic acid 8.0%9.0% 3.0%5.0%6.5% 1.7% 1.5% Product example 2b: Ramnolipid + 10% oleic acid7.0%4.0% 7.0%5.5%0.5%
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Disodium Lauryl Sulfosuccinate 5.0% 2.0% Lauryl sulfatesodium - - - - - - - - - 6.0% Cocamidopropyl betaine - 5.0% - - - - 2.5% - 6.0% 2.5% Coconut betaine - - - 2.0% - - 2.0% - 1.0% - Glycosidelaurila - - - - 3.0% 2.0% - 4.5% 4.5% - Cocoil sodium glutamate - - 3.5% - 1.5% 1.0% - - - - Lauroyl sarcosinatesodium 0.9%1.0% 2.5% Cocoyl isethionatesodium1.0% Cocoatesucrose 0.5% 1.0% 0.3% 1.0% - - 1.0% 1.0% 0.1% 0.5% Caprate ofpolyglyceryl-3 - - 1.0% - - - - - - - Alcohol - - - - 0.3% 0.1% - - - - Glycerin - - 0.5% - 5.0% 2.0% - 3.5% - - Polyquaternum-10 0.2% 0.2% 0.2% 0.2% 0.2% 0.2% 0.2% 0.3% 0.3% 0.2% Dimethicone 0.5% Protein fromwheathydrolyzed 0.2%0.1%0.1% 0.1%
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Glycol distearate - - 0.5% - 0.3% - 0.5% - - - Carbomer 1.0% - - - 0.5% - - - - - Hydroxide q.s. - - - 2.5% - - -- sodium, 10% Isoestearamide - 1.5% - - - - - - 1.5% 1.2% MIPA; iaurate of glycerol Cocamide DEA - 0.5% - 0.5% - 1.2% 2.0% - - 0.3% Sodium chloride 1.0% 1.0%0.5%1.5%2.0% 0.3% 0.2% PEG-120 dioleate 0.3% - - - - - - - - - of methyl glucose Xanthan gum - - 0.9% - 1.0% 0.3% - 1.0% - - Creatine 0.5% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% Citric acid ad pH 5.2 Preserving, q.sperfume. dyes
Table 85: List of raw materials used:
INCI Name: Commercial name: Fatty alcohols:Cetyl alcohol TEGO Alkanol 16, EvonikIndustries AG, 100% Thickeners / stabilizers:Carbomer TEGO Carbomer 140, EvonikIndustries AG, 100% Hydroxyethylcellulose Natrosolhydroxyethylcellulose, AshlandAqualon
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Cross-linked polymersacrylate / C10-3- alkyl acrylate inin TEGO Carbomer 341 ER, Evonik Industries AG, 100% Cocamide DEAREWOMID DC 212 S, Evonik Industries AG, 100%Cocamide MEAREWOMID D 212, Evonik Industries AG, 100%Isoestearamide MIPA, laurate ANTIL SPA 00O Evonik glycerolIndustries AG, 100%Sorbitan Sesquicaprilat ANTIL Soft SC, Evonik Industries AG, 100%Laureth-4TEGO Alkanol L 4, Evonik Industries AG, 100%PEG-60isoestearato in Emalex GWIS _160N, Nihon glycerolEmulsion CompanyPEG-150 distearateREWOPAL PEG 6000 DS, Evonik Industries AG, 100%PEG-120 methyl dioletate ANTIL 120 Plus, Evonik glucoseIndustries AG, 100%PEG-18 oleate / cocoate in ANTIL 171, Evonik Industries glycerolAG, 100% PEG-200 glycerol palmate REWODERM LI S 80, Evonik hydrogenated, PEG-7 cocoate in Industries AG, 100%glycerol Xanthan gumKeltrol CG-SFT, CP Kelco, 100% Pearlizing agents:PEG-3 distearate Cutina TS, BASF Cognis , 100% Glycol distearate TEGIN G 110, Evonik
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Industries AG, 100% Glycol distearate, Laureth-4, cocamidopropyl betaine TEGO Pearl N 300, EvonikIndustries AG Silicones:Amodimethicone DC 949, Dow Corning, 100% Dimethicone ABIL 350, Evonik IndustriesAG, 100% Dimethicone and Dimethicone DC 1503, Dow Corning Quaternium-80 ABIL Quat 32720, EvonikIndustries AG, 30% Silicone Quaternium-22 ABIL T Quat 60, EvonikIndustries AG, 65% Dimethicone Propyl PG-betaine ABIL B 9950, EvonikIndustries AG, 30% Methoxy PEG / PPG-7/3aminopropyl dimethicone ABIL Soft AF 100, EvonikIndustries AG, 100% Bis-PEG / PPG-20/20 dimethicone ABIL B 8832, EvonikIndustries AG, 100% PEG-PPG-14/4 dimethicone ABIL B 8851, EvonikIndustries AG, 95% Care polymer / film formersPolyquaternium-7 Merquat 550, Nalco, 100% Polyquaternium-10 Polymer JR-400, Amerchol,100% Copolymer ofstyrene / acrylates Yodosol GH840, Akzo Nobel Starch chloride Sensomer CI-50, Nalco
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hydroxypropyltrimonyHydroxypropyl guar Jaguar C-162, Rhodia, 100% ChloridehydroxypropyltrimonyActive ingredients:Panthenol D-Panthenol USP, BASF, 100% Allantoin Allantoin, DSM Tocopheryl acetate Tinoderm E, BASF Inulin Inutec H25, Beneo-Remy Niacinamide Niacinamide, USP, DSMNutrional Products, 100% Creatine TEGO Cosmo C 100, EvonikIndustries AG, 100% Sodium lactate, sodium PCA, glycine, fructose, urea, niacinamide, inositol, sodium benzoate, lactic acid LACTIL, Evonik IndustriesAG, 100% Salicylic acid AEC Salicylic Acid, A & EConnock Hydrolyzed wheat protein Gluadin WLM, BASF Cognis Anti-dandruff active ingredientsClimbazole Crinipan AD, Haasrmann &Reimer Fragrance GmbH, 100% Octopirox Octopirox, Clariant Zinc pyrithione Zinc-Pyrion NF, WeylChem,48% ConditionersCetrimonium chloride VARISOFT 300, Evonik
79/83
Industries AG, 30%Chloride in VARISOFT PATC, Evonik palmiramidopropyltrimônioIndustries AG, 60%Surfactants:Cocamidopropyl betaineTEGO Betain F 50, Evonik Industries AG, 38%Cocamidopropyl betaineTEGO Betain CK D, Evonik Industries AG, 82%Capril / capriamidopropylTEGO Betain 810, Evonik betaineIndustries AG, 35%Undecylenamidopropyl betaine REWOTERIC AM B U 185, Evonik Industries AG, 30% Coconut betaineDehyton AB 30, BASF Cognis, 31% Sodium cocoamfoacetateREWOTERIC AM ç, Evonik Industries AG, 32%Sodium cocoamphopropionate REWOTERIC AM KSF 40, Evonik Industries AG, 40%Disodium ricinoleamide REWODERM S 1333, Evonik MEA-sulfosuccinateIndustries AG, 40%Lauryl sulfosuccinate in REWOPOL SB F 12P, Evonik disagreementIndustries AG, 95%Laureth sulfosuccinate in REWOPOL SB FA 30 B, Evonik disagreementIndustries AG, 40%PEG-5 lauryl citrate REWOPOL SB c 55, Evonik disodium sulfosuccinateIndustries AG, 54%Sodium Laureth SulfateTexapon NSO, BASF Cognis, 28% Sodium lauryl sulfate Texapon LS 35, BASF Cognis,
80/83
30% Myreth sodium sulfate Texapon K 14S Spez, BASFCognis, 70% Ammonium Laureth Sulphate Standapol EA-1, BASF Cognis Sodium coco sulfate Texapon HC G, BASF Cognis Trideceth sodium sulfate Rhodapex EST-30, Rhodia Ammonium Lauryl Sulfate Standapol A, BASF Cognis MIPA-Laureth sulfate Zetesol 2056, Zschimmer &Schwarz GmbH Hydroxisultaine OriStar HSB, Orient StarsLLC Cacamidopropyl hydroxisultaine Mirataine CBS, Rhodia Lauryl glycoside Plantacare 1200 UP, BASFCognis, 50% Decyl glycoside Plantacare 2000 UP, BASFCognis Coconut glycoside Plantacare 818 UP, BASFCognis, 51% Glycosidecaprilila / caprila Plantacare 810 UP, BASFCognis Glyceryl glycoside Hydagen GG, BASF Cognis Cocoil sodium glutamate Plantapon ACG HC, BASFCognis Cocoil disodium glutamate Plantapon ACG LC, BASFCognis Hydrolyzed wheat protein cocoil sodium glutamate PGFAC-S, BASF Cognis
81/83
Lauroamfoglicinato Miranol Ultra L-21, Rhodia Sodium cocoyl glycinate Hostapo SG, Clariant Sodium Lauryl Sulfoacetate,Laureth sulfosuccinatedisagreement Stepan-Mild LSB, Stepan C14-16 define sodium sulfonate Bioterge AS-40 AOS, Stepan C12-15 Pareth-15 sodium sulfonate Avanel S-150 CGN, BASF Sodium anisate, sodium levulinate Dermosoft 1388, Dr.Straetmans Coco-glycoside sodium tartrate Eucarol AGE / ET, CesalpinaChemicals S.P.A. Sodium lauroyl lactylate Dermosoft SLL, Dr.Straetmans Sodium lauroyl sarcosinate Crodasinic LS 30, Croda, 30% Sodium cocoyl sarcosinate Crodasinic CS, Croda Miristoil sarcosinatesodium Crodasinic MS, Croda Lauroil sarcosina Crodasinic L, Croda C12-14 hydroxyalkylhydroxyethyl sarcosine Softazoline LMEB, KawakenFine Chemical Co. Methyl cocoyl sodium taurate Adinol CT, Croda Cocoil sodium alaninate Amilite ACS-12, Ajinomoto Sodium Lauryl Glucose Carboxylate Plantapon SF, BASF Cognis Sodium amfoacetate cocoa butter Mackem 1CXB, Rhodia Phosphate chloride Arlasik PTC, Croda
82/83
PG-dimonium cocamidopropyl Sodium lauroyl methyl isethionate Iselex,Chemicals Innospec Active Sodium cocoyl isethionate Hostapon STCI-85 P, Clariant Agents overfat / emollients: Polyglyceryl-3 caprate TEGOSOFT PC 31, EvonikIndustries AG, 100%Glyceryl caprylate Dermosoft GMCY, Dr.Straetmans Glyceryl stearate TEGIN 4100 Pellets , EvonikIndustries AG, 100%Glyceryl oleate TEGIN 0 V, Evonik IndustriesAG, 100% Diethylhexyl carbonate TEGOSOFT DEC, EvonikIndustries AG, 100%Triglyceride TEGOSOFT CT, Evonik caprilic / capric Industries AG, 100%PEG-7 glycerol cocoate TEGOSOFT GC, EvonikIndustries AG, 100%Sucrose cocoate TEGOSOFT APM, EvonikIndustries AG, 100%Sorbitol Sorbitol USP Powder, Lipo Glycerin Glycerol EP, vegetable, SpigaNord, 99.7%Hydrogenated didecene Satin Touch HD 2, ChevronPhillips Tipprilileter Cetiol OE, BASF Cognis Foam reinforcer:
83/83
Hydroxypropyl methylcellulose TEGOCEL HPM 50, EvonikIndustries AG, 100% Solubilizers:PEG-40 Castor Oilhydrogenated TAGAT CH 40, EvonikIndustries AG, 100% PEG-20 glyceryl laurate TAGAT L 2, Evonik IndustriesAG, 100% Pentylene glycol Hydrolite-5 616751, Symrise Polysorbate 20 TEGO SML 20, EvonikIndustries AG, 100% Polyglyceryl-4 caprate TEGOSOFT PC-41, EvonikIndustries AG, 100%
1/3

权利要求:
Claims (11)
[1]
1. Composition comprising water, at least one biotensoactive and at least one fatty acid characterized by the fact that the fraction of the sum of all surfactants in the composition is 1 to 30% by weight and the fraction of fatty acid, based on the sum of the acids fatty and surfactants, be 0.1 to 20% by weight;
wherein the composition has as biotensoatives, mono-, di- or polyamynolipids and / or soforolipids or any combination thereof;
in which the composition further comprises at least one surfactant which is not a biotensoative selected from the group consisting of anionic surfactants, amphoteric surfactants, ampholytic surfactants, zwitterionic surfactants and their combinations, and in which the fatty acid is β-hydroxydecanoic acid, dimeric acid oleic, palmitic acid, stearic acid and / or linoleic acid.
[2]
2. Composition, according to claim 1, characterized in that the composition comprises at least one thickener.
[3]
3. Composition, according to claim 2, characterized by the fact that the fraction of at least one thickener in the composition is of
0.1 to 10% by weight, based on composition.
[4]
4. Composition according to the claim
2 or 3, characterized by the fact that the composition has one or more PEG-free thickeners, selected from polysaccharides, celluloses, cellulose derivatives, alkyl modified sugar derivatives, carbomers,
Petition 870180124766, of 9/3/2018, p. 9/11
2/3 cross-linked polyacrylates, polyacrylamides, polyvinyl alcohol and polyvinylpyrrolidone, ethoxylated fatty acid glycerides, fatty acid esters with polyols, fatty alcohol ethoxylates and alkyl oligoglycosides.
[5]
Composition according to any one of claims 1 to 4, characterized in that the weight ratio of biotensives to surfactants that are not a biotensate is> 1: 1.
[6]
6. Composition according to any one of claims 1 to 4, characterized in that the weight ratio of biotensoactives to surfactants that are not a biotensive is 1: 1.
[7]
Composition according to any one of claims 1 to 6, characterized in that the composition does not comprise surfactants that contain sulfates or polyethylene glycol.
[8]
8. Composition according to any one of claims 1 to 7, characterized in that the composition has one or more natural dyes.
[9]
9. Composition according to any one of claims 1 to 8, characterized in that the composition is free of preservatives according to INCI.
[10]
10. Composition according to any one of claims 1 to 9, characterized in that the composition comprises propylene glycol, urea, glycerol, oils
essential, alcohol phenylethyl, ethanol or any combination of these. 11. Composition, according with any an of claims 1 to 10, characterized by fact gives composition have oils of perfumes or fragrances , where
Petition 870180124766, of 9/3/2018, p. 11/10
3/3 fraction of natural fragrances, based on the total number of
fragrances in oils of perfume, be at least 50% in Weight. 12. Composition, according with any an of claims 1 to 11, characterized by fact gives composition be a composition of treatment of body, gives
skin or hair.
[11]
13. Use of a composition, as defined in any one of claims 1 to 12, characterized in that it is as or for the production of bath additives, shower gel, shampoos, conditioners, body cleaning products, impregnation solutions for tissues moisturizers or skin cleansers.

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同族专利:

---

公开号 | 公开日

---

CN104125821A|2014-10-29|

---

WO2013098066A2|2013-07-04|

---

BR112014016225A8|2017-07-04|

---

US9271908B2|2016-03-01|

---

DE102011090030A1|2013-07-04|

---

JP2015507626A|2015-03-12|

---

WO2013098066A3|2014-08-28|

---

BR112014016225A2|2017-06-13|

---

US20140349902A1|2014-11-27|

---

CN104125821B|2017-04-12|

---

EP2797571A2|2014-11-05|

---

JP6155279B2|2017-06-28|

---

EP2797571B1|2019-07-24|

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法律状态:
2017-08-15| B25A| Requested transfer of rights approved|Owner name: EVONIK DEGUSSA GMBH (DE) |

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2018-06-05| B07A| Technical examination (opinion): publication of technical examination (opinion)|

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2018-11-21| B09A| Decision: intention to grant|

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2018-12-26| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/12/2012, OBSERVADAS AS CONDICOES LEGAIS. |

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2020-05-12| B25D| Requested change of name of applicant approved|Owner name: EVONIK OPERATIONS GMBH (DE) |

优先权:

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申请号 | 申请日 | 专利标题

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DE102011090030.6|2011-12-28|

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DE102011090030A|DE102011090030A1|2011-12-28|2011-12-28|Aqueous hair and skin cleansing compositions containing biosurfactants|

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PCT/EP2012/075024|WO2013098066A2|2011-12-28|2012-12-11|Aqueous hair and skin cleaning compositions comprising biotensides|

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